The only way that I am aware of is to test the system by running the F110 payment program to pay some relevant open invoices that will require bank chains and produce PAYEXT IDocs to see if the bank chains are populated in the IDoc. If the bank chains are set up correctly, the intermediary bank information will be populated into segment E2IDB02 with qualifier "T1", "T2" or "T3" depending on if the bank chain banks are Sender Correspondence Banks, Intermediary Banks or Recipient Correspondence Banks, respectively.
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