Here's a way that is just as easy: Define a file port with SM21 first and a new logical destination for this in table TBDLS (all this can be accessed via transaction SALE). Then define a simple ALE scenario that sends MATMAS to the newly defined destination. Create partner profiles automatically from SALE and transfer IDocs with BD10.
If you like programming, even easier is:
Call MASTERIDOC_MATMAS_REQ for your material and download the received table content with GUI_DOWNLOAD (or WS_DOWNLOAD in older releases)
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